Domino electroreduction of CO2 to methanol on a molecular catalyst

  • 1.

    Costentin, C., Robert, M. & Savéant, J.-M. Catalysis of the electrochemical reduction of carbon dioxide. Chem. Soc. Rev. 42, 2423–2436 (2013).

  • 2.

    Schiffer, Z. J. & Manthiram, K. Electrification and decarbonization of the chemical industry. Joule 1, 10–14 (2017).

  • 3.

    Francke, R., Schille, B. & Roemelt, M. Homogeneously catalyzed electroreduction of carbon dioxide—methods, mechanisms, and catalysts. Chem. Rev. 118, 4631–4701 (2018).

  • 4.

    Hori, Y., Wakebe, H., Tsukamoto, T. & Koga, O. Electrocatalytic process of CO selectivity in electrochemical reduction of CO2 at metal electrodes in aqueous media. Electrochim. Acta 39, 1833–1839 (1994).

  • 5.

    Hori, Y. in Modern Aspects of Electrochemistry Vol. 42 (eds Vayenas, C. G. et al.) 89–189 (Springer, 2008).

  • 6.

    Peterson, A. A., Abild-Pedersen, F., Studt, F., Rossmeisl, J. & Nørskov, J. K. How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels. Energy Environ. Sci. 3, 1311–1315 (2010).

  • 7.

    Peterson, A. A. & Nørskov, J. K. Activity descriptors for CO2 electroreduction to methane on transition-metal catalysts. J. Phys. Chem. Lett. 3, 251–258 (2012).

  • 8.

    Zhang, X. et al. Highly selective and active CO2 reduction electrocatalysts based on cobalt phthalocyanine/carbon nanotube hybrid structures. Nat. Commun. 8, 14675 (2017).

  • 9.

    Varela, A. S. et al. Metal-doped nitrogenated carbon as an efficient catalyst for direct CO2 electroreduction to CO and hydrocarbons. Angew. Chem. Int. Ed. 54, 10758–10762 (2015).

  • 10.

    Shen, J. et al. Electrocatalytic reduction of carbon dioxide to carbon monoxide and methane at an immobilized cobalt protoporphyrin. Nat. Commun. 6, 8177 (2015).

  • 11.

    Wu, Y., et al. Electroreduction of CO2 catalyzed by a heterogenized Zn–porphyrin complex with a redox-innocent metal center. ACS Cent. Sci. 3, 847–852 (2017).

  • 12.

    Pan, Y. et al. Design of single-atom Co–N5 catalytic site: a robust electrocatalyst for CO2 reduction with nearly 100% CO selectivity and remarkable stability. J. Am. Chem. Soc. 140, 4218–4221 (2018).

  • 13.

    Tripkovic, V. et al. Electrochemical CO2 and CO reduction on metal-functionalized porphyrin-like graphene. J. Phys. Chem. C 117, 9187–9195 (2013).

  • 14.

    Ju, W. et al. Understanding activity and selectivity of metal-nitrogen-doped carbon catalysts for electrochemical reduction of CO2. Nat. Commun. 8, 944 (2017).

  • 15.

    Dhanasekaran, T., Grodkowski, J., Neta, P., Hambright, P. & Fujita, E. p-Terphenyl-sensitized photoreduction of CO2 with cobalt and iron porphyrins. Interaction between CO and reduced metalloporphyrins. J. Phys. Chem. A 103, 7742–7748 (1999).

  • 16.

    Fujita, E., Creutz, C., Sutin, N. & Szalda, D. J. Carbon dioxide activation by cobalt(I) macrocycles: factors affecting carbon dioxide and carbon monoxide binding. J. Am. Chem. Soc. 113, 343–353 (1991).

  • 17.

    Rao, H., Schmidt, L. C., Bonin, J. & Robert, M. Visible-light-driven methane formation from CO2 with a molecular iron catalyst. Nature 548, 74 (2017).

  • 18.

    Leonard, N. et al. The chemical identity, state and structure of catalytically active centers during the electrochemical CO2 reduction on porous Fe–nitrogen–carbon (Fe–N–C) materials. Chem. Sci. 9, 5064–5073 (2018).

  • 19.

    Zhang, H., Li, J., Cheng, M.-J. & Lu, Q. CO Electroreduction: current development and understanding of Cu-based catalysts. ACS Catal. 9, 49–65 (2018).

  • 20.

    Solis, B. H., Maher, A. G., Dogutan, D. K., Nocera, D. G. & Hammes-Schiffer, S. Nickel phlorin intermediate formed by proton-coupled electron transfer in hydrogen evolution mechanism. Proc. Natl Acad. Sci. USA 113, 485–492 (2016).

  • 21.

    Jiang, J. et al. Unusual stability of a bacteriochlorin electrocatalyst under reductive conditions. A case study on CO2 conversion to CO. ACS Catal. 8, 10131–10136 (2018).

  • 22.

    Grodkowski, J. et al. Reduction of cobalt and iron phthalocyanines and the role of the reduced species in catalyzed photoreduction of CO2. J. Phys. Chem. A 104, 11332–11339 (2000).

  • 23.

    Lieber, C. M. & Lewis, N. S. Catalytic reduction of carbon dioxide at carbon electrodes modified with cobalt phthalocyanine. J. Am. Chem. Soc. 106, 5033–5034 (1984).

  • 24.

    Zhang, Z. et al. Reaction mechanisms of well-defined metal–N4 sites in electrocatalytic CO2 reduction. Angew. Chem. Int. Ed. 57, 16339–16342 (2018).

  • 25.

    Kapusta, S. & Hackerman, N. Carbon dioxide reduction at a metal phthalocyanine catalyzed carbon electrode. J. Electrochem. Soc. 131, 1511–1514 (1984).

  • 26.

    Boutin, E. et al. Aqueous electrochemical reduction of carbon dioxide and carbon monoxide into methanol with cobalt phthalocyanine. Angew. Chem. Int. Ed. 58, 16172 (2019).

  • 27.

    Aoi, S., Mase, K., Ohkubo, K. & Fukuzumi, S. Selective electrochemical reduction of CO2 to CO with a cobalt chlorin complex adsorbed on multi-walled carbon nanotubes in water. Chem. Commun. 51, 10226–10228 (2015).

  • 28.

    Hu, X.-M., Rønne, M. H., Pedersen, S. U., Skrydstrup, T. & Daasbjerg, K. Enhanced catalytic activity of cobalt porphyrin in CO2 electroreduction upon immobilization on carbon materials. Angew. Chem. Int. Ed. 56, 6468–6472 (2017).

  • 29.

    Achar, B. N. & Lokesh, K. S. Studies on tetra-amine phthalocyanines. J. Organomet. Chem. 689, 3357–3361 (2004).

  • 30.

    Ding, X. & Han, B.-H. Metallophthalocyanine-based conjugated microporous polymers as highly efficient photosensitizers for singlet oxygen generation. Angew. Chem. Int. Ed. 54, 6536–6539 (2015).

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